JEE Main 2026 — General Organic Chemistry Question with Solution
JEE Main 2026 (23 January Shift 2)
Question
Given below are two statements:
Statement I: is more stable than as nine hyperconjugation interactions are possible in .
Statement II: is less stable than as only three hyperconjugation interactions are possible in .
In the light of the above statements, choose the correct answer from the options given below
Statement I: is more stable than as nine hyperconjugation interactions are possible in .
Statement II: is less stable than as only three hyperconjugation interactions are possible in .
In the light of the above statements, choose the correct answer from the options given below
Choose an option
Show full solutionCorrect option: B
Correct answer
BStatement I is true but Statement II is false
Step-by-step explanation
Statement I: In the tert-butyl carbocation , there are three methyl groups attached to the carbocationic carbon. Each methyl group has 3 -hydrogens, making a total of 9 -hydrogens. Thus, 9 hyperconjugation interactions are possible, which significantly stabilize the carbocation. Statement I is true.
Statement II: In the methyl carbocation , there are no -carbons and consequently no -hydrogens. Hyperconjugation requires the presence of at least one -hydrogen on a carbon adjacent to the hybridized carbocation center. Therefore, zero hyperconjugation interactions are possible in . Statement II is false because it claims three hyperconjugation interactions are possible.
Conclusion: Statement I is true but Statement II is false.
Statement II: In the methyl carbocation , there are no -carbons and consequently no -hydrogens. Hyperconjugation requires the presence of at least one -hydrogen on a carbon adjacent to the hybridized carbocation center. Therefore, zero hyperconjugation interactions are possible in . Statement II is false because it claims three hyperconjugation interactions are possible.
Conclusion: Statement I is true but Statement II is false.
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This is a previous-year question from JEE Main 2026, covering the General Organic Chemistry chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.