JEE Main 2022 — Haloalkanes And Haloarenes Question with Solution
From: JEE Main 2022 (Online) 28th June Evening Shift
Question
The major product of the following reaction contains ____________ bromine atom(s).
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Step-by-step explanation

Here only carbon 12th and 13th is not taking part in the resonance. All other carbons are taking part in resonance and lone pair of O is also taking part in the resonance.
As because of resonance stability of compound increases Br will not attack to any carbon which is taking part in the resonance and decrease the stability of compound.
So, Br can only attack 12th carbon or 13th carbon atom but 12th carbon is a alpha carbon and it can easily donate H+ ion and add Br- ion and increase stability.
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This is a previous-year question from JEE Main 2022, covering the Haloalkanes And Haloarenes chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.