JEE Main 2023 — Haloalkanes and Haloarenes Question with Solution
JEE Main 2023 (29 Jan Shift 1)
Question
Identify the correct order for the given property for following compounds

Choose the correct answer from the option given below :-
Choose an option
Show full solutionCorrect option: B
Step-by-step explanation
The boiling point of organic compounds depends on two factors:
(i) Molecular weight: Boiling point increases with increase in molecular weight.
(ii) Intermolecular forces: Higher the strength of intermolecular forces, higher is the boiling point.
As the mass of the compound increases then their boiling point will also increase. Hence, (A) and (C) are correct.
Density of Et-Cl = 0.89 g/ml
Et-Br = 1.47 g/ml
Et-I = 1.94 g/ml
Density of halides increases with number of carbon atoms and at mass of halogen present. So, (B) and (D) is incorrect.
As branching of the compound increases then boiling point decreases. Hence, (E) is correct.
So, the correct answer is (A), (C) and (E) only.
Practice this on the real CBT interface
Solve this JEE Main question (and the rest of the Haloalkanes and Haloarenes chapter) on PrepSharp's TCS iON-style CBT player — with timer, bookmarks and session analytics.
Solve interactively →About this question
This is a previous-year question from JEE Main 2023, covering the Haloalkanes and Haloarenes chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.