JEE Main 2025 — Hydrocarbons Question with Solution
From: JEE Main 2025 (Online) 29th January Evening Shift
Question
Isomeric hydrocarbons → negative Baeyer’s test
(Molecular formula C9H12)
The total number of isomers from above with four different non-aliphatic substitution sites is -
Enter your answer
Show full solutionCorrect answer: —
Step-by-step explanation
Molecular formula of isomeric hydrocarbon - Negative Baeyer's test
Baeyers test is given by compounds that contain readily active carbon-carbon double bond.
So, in a negative Baeyer's test, there is no readily active c = c.
Compounds that give negative Baeyer's test are alkanes and aromatic compounds.
CH compound is not an alkane
(Alkane general formula CH)
Hydrocarbons with the formula CH are considered as aromatic and isomers of substituted benzene rings.
The possible isomers of CH are

From these, total number of the isomers with four different non-aliphatic substitution sites are 2
![]() |
![]() |
![]() |
| Four positions (1,2,3,4) are different. So, it contain four different non-aliphatic substitution sites. | Four position (1,2,3,4) are different. So, it contain four different non-aliphatic substitution sites. | Four position (1,2,3,4) are not different. So, it contain four different non-aliphatic substitution sites. |
Practice this on the real CBT interface
Solve this JEE Main question (and the rest of the Hydrocarbons chapter) on PrepSharp's TCS iON-style CBT player — with timer, bookmarks and session analytics.
Solve interactively →About this question
This is a previous-year question from JEE Main 2025, covering the Hydrocarbons chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.


