JEE Main 2024Chemistryp Block Elements (Group 15, 16, 17 & 18)EasyMCQ

JEE Main 2024p Block Elements (Group 15, 16, 17 & 18) Question with Solution

JEE Main 2024 (30 Jan Shift 2)

Question

Choose the correct statements about the hydrides of group 15 elements.
A. The stability of the hydrides decreases in the order NH3>PH3>AsH3>SbH3>BiH3
B. The reducing ability of the hydrides increases in the order NH3<PH3<AsH3<SbH3<BiH3
C. Among the hydrides, NH3 is strong reducing agent while BiH3 is mild reducing agent.
D. The basicity of the hydrides increases in the order NH3<PH3<AsH3<SbH3<BiH3

Choose the most appropriate from the option given below:

Choose an option

Show full solutionCorrect option: C
Correct answer
CA and B only

Step-by-step explanation

On moving down the group from N to Bi, the atomic size increases. Consequently, the electron density on the central atom decreases and the basic strength decreases.

With an increase in size, the M-H bond becomes weaker, hence, the thermal stability decreases down the group.

The highest bond length will have less bond energy, indicating that it is a strong reducing agent.

On moving down the group, bond strength of M–H bond decreases, which reduces the thermal stability but increases reducing nature of hydrides,

Hence A and B are correct statements. 

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About this question

This is a previous-year question from JEE Main 2024, covering the p Block Elements (Group 15, 16, 17 & 18) chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.