JEE Main 2020ChemistrySolutionsDepression In Freezing PointmediumNumerical

JEE Main 2020Solutions Question with Solution

From: JEE Main 2020 (Online) 9th January Evening Slot

Question

A cylinder containing an ideal gas (0.1 mol of 1.0 dm3) is in thermal equilibrium with a large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the stoppers S1 and S2 (as shown in the figure) are suddenly withdrawn, the volume of the gas in litres after equilibrium is achieved will be____.

(Given, Kf (water) = 2.0 K kg mol–1,
R = 0.08 dm3 atm K–1 mol–1)

JEE Main 2020 (Online) 9th January Evening Slot Chemistry - Solutions Question 116 English

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Show full solutionCorrect answer: 2.18
Correct answer
2.18

Step-by-step explanation

For aqueous solution

Tf = Kf.m = 2 × 0.5

Temperature of solution = –1°C = 272 K

Final volume of ideal gas =

=

= 2.18 L

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