JEE Main 2014ChemistryStates of MatterMediumMCQ

JEE Main 2014States of Matter Question with Solution

JEE Main 2014 (06 Apr)

Question

If Z is the compressibility factor, then Van der Waal's equation at low pressure can be written as:

Choose an option

Show full solutionCorrect option: B
Correct answer
B Z = 1 - a VRT

Step-by-step explanation

Van der Waal's Equation of state for one mole

P + a V 2 V - b = RT

At low pressure, the characteristic constant (a) becomes significant whereas (b) becomes negligible. So (b) is ignored.

P + a V 2 V = RT

PV + a V = RT

PV RT = RT RT - a VRT = 1 - a VRT

At low pressure for most gases z < 1.

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About this question

This is a previous-year question from JEE Main 2014, covering the States of Matter chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.