JEE Main 2023 — Structure Of Atom Question with Solution
From: JEE Main 2023 (Online) 8th April Morning Shift
Question
The number of following statement/s which is/are incorrect is ___________
(A) Line emission spectra are used to study the electronic structure
(B) The emission spectra of atoms in the gas phase show a continuous spread of wavelength from red to violet
(C) An absorption spectrum is like the photographic negative of an emission spectrum
(D) The element helium was discovered in the sun by spectroscopic method
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Step-by-step explanation
(A) This statement is correct. Line emission spectra (or atomic emission spectra) are indeed used to study the electronic structure of atoms. These spectra are produced when photons are emitted from atoms as excited electrons return to a lower energy level. Each line corresponds to a particular quantum leap between energy levels.
(B) This statement is incorrect. The emission spectra of atoms in the gas phase do not show a continuous spread of wavelength from red to violet. Instead, they show distinct lines corresponding to specific electron transitions, hence they are known as line emission spectra.
(C) This statement is correct. An absorption spectrum is like the photographic negative of an emission spectrum. In an absorption spectrum, light passes through a cold, dilute gas and atoms in the gas absorb at characteristic frequencies; since the re-emitted light is unlikely to be emitted in the same direction as the absorbed photon, this gives rise to dark lines (absence of light) in the spectrum.
(D) This statement is correct. The element helium was indeed discovered in the sun through spectroscopy before it was found on Earth. The name helium comes from Helios, the Greek name for the sun.
So, the number of incorrect statements is 1.
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This is a previous-year question from JEE Main 2023, covering the Structure Of Atom chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.