JEE Main 2021ChemistryCoordination CompoundsWarners Theory And Valence Bond TheorymediumNumerical
JEE Main 2021 — Coordination Compounds Question with Solution
From: JEE Main 2021 (Online) 20th July Evening Shift
Question
An aqueous solution of NiCl2 was heated with excess sodium cyanide in presence of strong oxidizing agent to form [Ni(CN)6]2−. The total change in number of unpaired electrons on metal centre is _______________.
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▸Show full solutionCorrect answer: 2
Correct answer
2
Step-by-step explanation
[Ni(CN)6]2-
Ni+4→ d6, CN- strong field ligand. So pairing will happen.
Here zero unpaired electron
NiCl2→ Ni2+→ d8
Cl- Weak field ligand.→ two unpaired e-
∴ Change = 2.
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