JEE Main 2020ChemistryCoordination CompoundsCrystal Field Theory CftmediumMCQ
JEE Main 2020 — Coordination Compounds Question with Solution
From: JEE Main 2020 (Online) 3rd September Evening Slot
Question
The d-electron configuration of [Ru(en)3
]Cl2 and [Fe(H2O)6]Cl2
, respectively are :
Choose an option
▸Show full solutionCorrect option: C
Correct answer
Ct2g6eg0 and t2g4eg2
Step-by-step explanation
[Ru(en)3
]Cl2 :
Here CN = 6 so octahedral splitting happens.
'en' is strong field ligand so Δ0 > P(pairing energy). That is why pairing of electrons happens.
Δ0 = Energy gap between eg and t2g orbital.
[Fe(H2O)6]Cl2 :
Here CN = 6 so octahedral splitting happens.
H2O is weak field ligand so Δ0 < P(pairing energy). That is why no pairing of electrons happens.
Δ0 = Energy gap between eg and t2g orbital.
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