JEE Main 2021 — Coordination Compounds Question with Solution
From: JEE Main 2021 (Online) 24th February Evening Shift
Question
The calculated magnetic moments (spin only value) for species , and respectively are :
Choose an option
Show full solutionCorrect option: B
Correct answer
B4.90, 0 and 1.73 BM
Step-by-step explanation
(i) {[FeC{l_4}]^{2 - }}\buildrel {} \over
\longrightarrow F{e^{2 + }}\buildrel {} \over
\longrightarrow [Ar]3{d^6}
Cl is weak field ligand so does not pairing occur

So, magnetic moment
(n = Number of total unpaired e = 4)
(ii)
C2O4 is strong field ligand so pairing occur.

All electrons are paired, n = 0
hence, = 0
(iii)
Cl is weak field ligand so does not pairing occur

So, magnetic moment
(n = Number of total unpaired e = 4)
(ii)
C2O4 is strong field ligand so pairing occur.

All electrons are paired, n = 0
hence, = 0
(iii)
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