JEE Main 2020ChemistryCoordination CompoundsCrystal Field Theory CftmediumMCQ

JEE Main 2020Coordination Compounds Question with Solution

From: JEE Main 2020 (Online) 2nd September Morning Slot

Question

Consider that a d6 metal ion (M2+) forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex is

Choose an option

Show full solutionCorrect option: C
Correct answer
Ctetrahedral and –0.6 t

Step-by-step explanation

Spin only magnetic moment = 4.9 =

From this, n = 4 (unpaired electrons)

(A) In octahedral complex: [M(H2O)6] 2+ JEE Main 2020 (Online) 2nd September Morning Slot Chemistry - Coordination Compounds Question 227 English Explanation 1

C.F.S.E. = (–0.4 0) × 4 + (+0.6 0) × 2 + 0 × P
= –0.4 0

(B) In tetrahedral complex: [M(H2O)4] 2+

JEE Main 2020 (Online) 2nd September Morning Slot Chemistry - Coordination Compounds Question 227 English Explanation 2
C.F.S.E. = (–0.6 t) × 3 + (+0.4 t) × 3 + 0 × P
= –0.6 t

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About this question

This is a previous-year question from JEE Main 2020, covering the Coordination Compounds chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.