JEE Main 2022Chemistrys Block ElementsMediumMCQ

JEE Main 2022s Block Elements Question with Solution

JEE Main 2022 (26 Jul Shift 2)

Question

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : LiF is sparingly soluble in water. Reason R : The ionic radius of Li+ ion is smallest among its group members, hence has least hydration enthalpy.

In the light of the above statements, choose the most appropriate answer from the options given below.

Choose an option

Show full solutionCorrect option: C
Correct answer
CA is true but R is false

Step-by-step explanation

The low solubility of LiF in water is due to its high lattice enthalpy.

The hydration enthalpies of alkali metal ions in aqueous solution decreases with increase in ionic sizes.

Li+>Na+>K+>Rb+>Cs+

Li+ has maximum degree of hydration and for this reason lithium salts are mostly hydrated, e.g., LiCl.2H2O

Hence, A is true and R is false.

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About this question

This is a previous-year question from JEE Main 2022, covering the s Block Elements chapter of Chemistry. PrepSharp catalogues every PYQ from JEE Main with a verified answer key and step-by-step solution prepared by IIT alumni — so you can search by chapter, topic or year and revise efficiently.